Low-friction flows of liquid at nanopatterned interfaces

Low-friction flows of liquid at nanopatterned interfaces.

With the important development of microfluidic systems, miniaturization of flow devices has become a real challenge. Microchannels, however, are characterized by a large surface-to-volume ratio, so that surface properties strongly affect flow resistance in submicrometre devices. We present here results showing that the concerted effect of wetting properties and surface roughness may considerabl...

Nanoscale friction mechanisms at solid-liquid interfaces.

1 IMETUM und Physik Department, TUM, Boltzmannstrasse 11, 85748 Garching. 2 Ernst-Berl Institut für Makromolekulare Chemie, TU Darmstadt, Petersenstrasse 22, 64287 Darmstadt, Germany. Fig. 1: Observed nanoscale friction mechanisms. A single polymer molecule at a solidliquid interface can respond in different ways to a lateral external force, here exerted by an AFM cantilever tip (depicted in ye...

Toward generating low-friction nanoengineered surfaces with liquid-vapor interfaces.

Using molecular dynamics (MD), we investigate the importance of liquid-vapor interface topography in designing low-friction nanoengineered superhydrophobic surfaces. Shear flow is simulated on patterned surfaces. The relationship between the effective slip length and bubble meniscus curvature is attained by generating entrapped bubbles with large protrusion angles on patterned surfaces with nan...

Colloids at Liquid-liquid Interfaces

Hydrogen evolution at liquid-liquid interfaces.

Blowing bubbles: Hydrogen evolution by proton reduction with [(C(5)Me(5))(2)Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C(5)Me(5))(2)Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqu...